トリアルキルシリルトリフラートを用いる有機合成
1982 年 40 巻 6 号 p. 534-544
詳細
1982 年 40 巻 6 号 p. 534-544
Trialkylsilyl triflates are a new class of super-reagents, which act as efficient agents for silylation of active hydrogen compounds and catalysts of nucleophilic addition and displacement reactions in aprotic media. The synthetic utility is exemplified by a variety of functional group transformations and carbon-carbon bond-forming reactions. Immobilization of the silyl reagent on a resinsulfonic acid is also described.
