錯体触媒を用いる1, 3-ジエンオリゴマーの合成における選択性

抄録

Dimers and trimers of 1, 3-dienes can be readily produced using various transition metal complexes as the catalyst. This oligomerization affords linear and cyclic isomers, each of which is further divided into cis or trans isomers concerning the position of the remaining double bonds.
This paper deals with the effect of the transition metal catalyst particularly, the electronic and steric effects of the ligand combined with the transition metal on the oligomer distribution. In this article we describe a trial to predict the selectivity and reactivity of 1, 3-dienes according to the LFER method.