(アレーン) トリカルボニルクロム (0) 錯体を触媒とする還元反応
カルバサイクリン類合成への応用を中心として
1985 年 43 巻 9 号 p. 877-890
詳細
1985 年 43 巻 9 号 p. 877-890
Characteristic functions of arene·Cr (CO) 3 complexes as catalysts for the hydrogenation of multiple bonds such as 1, 3-dienes (to internal monoenes), alkynes (to cis-alkenes), and α, β-unsaturated carbonyl compounds (to saturated analogs) are reviewed. Application of these hydrogenation reactions to highly stereoselective syntheses of biologically significant substances such as carbacyclins and pheromone are also described.
