Journal of Synthetic Organic Chemistry, Japan
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
Invention and Commercialization of New Selective Herbicide Quizalofop-Ethyl
Yasukazu URAGozyo SAKATA
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1990 Volume 48 Issue 10 Pages 921-928

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Abstract
Several derivatives of heterocyclic-oxy phenoxy propionic acid have been known as selective herbicides. During extensive investigations on this series with various condensed heterocyclic moieties, the quinoxalinyloxy phenoxy propionic acid derivatives were found to show an excellent herbicidal activity against grass weeds. Among them, ethyl 2- [4- (6-chloro-2-quinoxalinyloxy) phenoxy] propionate, (code No.NC-302, quizalofop ethyl) showed a potent herbicidal activity. It is commercialized as a novel post-emergence herbicide. In this paper, facile syntheses of substituted quinoxalines and quizalofop ethyl derivatives are described in detail.
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© The Society of Syhthetic Organic Chemistry, Japan
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