Samarium Diiodide-Mediated Reaction of Organic Halides with Carbonyl Compounds
1998 年 56 巻 11 号 p. 908-918
詳細
1998 年 56 巻 11 号 p. 908-918
The following three types of samarium diiodide mediated reactions qf organic halides and carbonyl compounds are discussed : 1) Samarium-mediated highly stereoselective reaction of 1, 1-dihaloalkanes with aldehydes. 2) Stereoselective reaction with configurationally stable α-phenylthioalkylsamarium compounds. 3) Preparation and reaction of a samarium enolate equivalent of β-ketoester.
