Journal of Synthetic Organic Chemistry, Japan
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
Recent Progress in the Morita-Baylis-Hillman Reactions
Yoshiharu Iwabuchi, Susumi Hatakeyama
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Keywords: Morita-Baylis-Hillman reaction, nucleophilic catalysis, rate enhancement, asymmetric synthesis, asymmetric catalysis, diastereoselective reaction, amine catalyst, phosphine catalyst, calcogeno-Baylis-Hiliman reactions, tandem Michael-aldol reaction, enzymatic resolution, kinetic resolution
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2002 Volume 60 Issue 1 Pages 2-14

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Abstract
The Morita-Baylis-Hillman reaction, α-hydroxyalkylation of activated olefins, has attracted considerable research interest because of the synthetic utility of the densely functionalized product as well as the exquisite tandem Michael-aldol reaction process under nucleophilic catalysis. This review gives an overview on recent remarkable progress in the Morita-Baylis-Hillman reactions. Several other successful methods affording the Morita-Baylis-Hillman type adducts are also reviewed by focusing their imaginative strategies.
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© The Society of Syhthetic Organic Chemistry, Japan
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