超高圧有機合成化学における最近の進歩

抄録

The great utility of high-pressure technology to achieve the desired reactions which are not readily accessible by other means and its application in natural product or material synthesis have been reviewed. Newly developed methods especially atom-economic processes for functional group transformations, environment-friendly constructions of target molecules, and promotion of sterically-restricted organic reactions are described. These include (1) Diels-Alder reaction, (2) intramolecular Diels-Alder reaction, (3) hetero-Diels-Alder reaction, (4) 1, 3-dipolar [3+2] cycloaddition reaction, (5) aldol condensation, (6) Friedel-Crafts-type alkylation, (7) Michael addition reaction, (8) S_N2-type substitution, (9) nucleophilic aromatic substitution, (10) epoxide ringopening reaction, (11) organometallic reaction, (12) Lewis acid-catalyzed reaction.