不活性sp³炭素-水素結合の触媒的官能基化

抄録

The catalytic transformation of inert C-H bonds to other functional groups is one of the most active research areas in organic and organometallic chemistry because such reactions present possibilities to exploit readily available starting materials, shorten reaction sequences, and synthesize compounds that are otherwise difficult to prepare. In this review, recent advances in the catalytic functionalization of unactivated sp³ C-H bonds are briefly introduced. The sp³ C-H bonds were transformed to C-C and C-O bonds through activation with transition metal catalysts assisted by chelation of directing groups or a cyclometalation process.