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有機合成化学協会誌
Vol. 66 (2008) No. 2 P 172-173

記事言語:

http://doi.org/10.5059/yukigoseikyokaishi.66.172


The enantionselective addition of terminal acetylenes to aldehydes or ketones affords a direct access to optically active propargyl alcohols which are useful, versatile synthetic intermediates. This mini review focuses on the recent advances in zinc (II) and indium (III) salts-mediated asymmetric alkynylation on carbonyl compounds via in situ "catalytic" generation of metal acetylide.

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