The glass bead preparation method specified in JIS R 5204 for X-ray fluorescence analysis of cement and the calibration curve method specified in JIS A 6201 for the XRF-briquette method were applied to five types of fly ash, and the SiO2, Al2O3, Fe2O3, Na2O, and K2O content was determined at four measuring institutions with three repetitions per sample. Although some laboratories need to review the procedure for glass bead preparation and improve the calibration curve setting accuracy for quantitative analysis using the XRF analyzer in order to improve the analysis accuracy, relatively high analysis accuracy was secured even when the briquette sample was replaced by the glass bead sample in the XRF analysis method of JIS A 6201. It was confirmed that the analysis of each of the Al2O3, Fe2O3, Na2O, and K2O components along with SiO2 is possible with relatively high analytical precision even when the briquette sample is replaced by a glass bead sample in the JIS A 6201 XRF analysis method.
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