This paper introduces the analytical methods of thermal analysis for hybrid rocket fuel, and of evolved gas analysis for flash pyrolysis products. The thermal characterization of solid fuels requires the evaluation of phase changes, pyrolysis products, and thermophysical properties. This study performed measurements using conventional analytical chemistry methods and qualitative measurements of pyrolysis products. Furthermore, the temperature profile near the fuel surface was obtained because accurate measurement of the combustion flame temperature is essential for evaluating the propellant performance. The thermal, evolved gas, and kinetic analyses were conducted to investigate the phase-change process on the fuel surface. Because multicomponent polymeric materials, such as LT fuel, can lead to complex responses, this study evaluates the phase change behavior in detail by directly observing the color and shape changes of the heated samples. To measure the flash pyrolysis products generated in a flash heating environment, direct and real-time measurements are essential because the pyrolysis products generated from the burning surface are highly active. Qualitative analysis was carried out using a Curie-point pyrolyzer and an ion attachment-mass spectrometer (IA/MS) with a skimmer interface to reduce fragmentation and the second reaction of the products.
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