Miocene sandstones recovered from three Ocean Drilling Program (ODP) sites in the Japan Sea backarc basin during ODP Legs 127/128 provide comparative data on albitization of feldspar subjected to different burial conditions. Feldspars in volcaniclastic sandstones from Site 796 in the northern Japan Basin (burial temperatures less than -60°C) have not been albitized. Feldspars at the other two sites are albitized to various degrees, depending upon burial temperature, original composition of the feldspars, and crystallographic features such as twinning, zoning, cleavage planes, glass inclusions, and micropores. At Site 797 (Yamato Basin), volcaniclastic sandstones have been subjected to temperatures ranging from -120 to >150°C, owing in part to intrusion by sills. About 50 percent of-450 plagioclase feldspar grains examined in 750 analyses by use of the electron probe microanalyzer have been partially or completely replaced by albite (>Ab
95). A small number of K-feldspar grains (<-1-2%) are also replaced in part of albite. Selective albitization has been facilitated by the presence of glass inclusions, micropores, and twin and cleavage planes. Sandstones at Site 799 (Yamato Rise) are arkoses that have undergone maximum diagenetic temperatures of about 90-100°C. About 25 percent of -500 plagioclase grains examined in-800 analyses have been altered totally or in part to albite. A few K-feldspar grains (-1%) have also been partially replaced by albite. Albitization was enhanced by the presence of twin and cleavage planes and fractures.
Albitization occurs by a dissolution-reprecipitation process. Single, large grains of plagioclase or K-feldspar are commonly replaced by numerous, micron-size, elongated albite crystals (laths), all orientated in roughly the same direction. The dissolution that precedes albitization typically proceeds along crystallographic planes and commonly occurs as a result of congruent (stoichiometric) dissolution processes. Ca-rich plagioclase is particularly susceptible to such albitization; essentially all plagioclase in Site 797 and 799 sandstones more calcic than An 50 has been albitized.
Albitization has changed original chemical composition and altered the twinning and zoning characteristics of many of the plagioclase feldspars from Site 797 and 799. These diagenetic changes have reduced the usefulness of the feldspars for provenance determination.
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