The effects of reaction time, pH and humic substances on the aqueous chlorination were studied with respect to the quantitative formation of dichloroacetic acid (DCA), trichloroacetic acid (TCA), chloral hydrate (CH), chloroform, and total organic chlorine (TOCl).
Humic acid was chlorinated at following conditions : total organic carbon 5mg·l
-1, chlorine dose 20mg·l
-1, reaction time (5min, 1, 6, and 24h), pH (4, 6, 7, 8, and 10), and at room temperature.
At the neutral pH, the concentration of DCA, TCA, and CH increased with the increase of reaction time similar to the case of chloroform or of TOCl. The amount of TCA formed was greater than chloroform.
The concentration of chloroform increased with increase of pH from 4 to 10. However, TCA and CH formation decreased at pH range of 810. The pH dependence of DCA and CH formation was smaller than the cases of chloroform and of TCA.
The DCA, TCA, and CH formation from fumic acid was similar to that from humic acid.
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