A few attempts for chromium to form a ferrite (ferritization) with iron(II) sulfate more tightly and to be removed from wastewater simultaneously were examined.
The treatment of the wastewater containing chromium less than 10mg·l
-1 was possible by the ferritization under the standard conditions, i.e., at pH of 9.0, temperature of 65 °C, reaction time of 60min and Fe(II) of 5g·l
-1. In the case of the wastewater containing chromium more than 10mg ·l
-1, the treatment was impossible by the standard conditions but possible by different conditions, i.e., at reaction time of 90min, Fe(II) of 10g·l
-1 and addition of aluminium of 0.1g·l
-1. After the treatment of 25mgCr·l
-1 solution, it was found that aluminium restrained the dissolution of chromium from the ferrite. In the case of solution of more than 50mgCr·l
-1, it was better to lower pH to 8.0, but it was hard to prevent chromium from dissolving by alteration of the conditions and even by the addition of aluminium. The best method to lower the amount of chromium dissolving was to lower drying temperature to less than 70°C.
A counterplan for unsuccessfully produced ferrite and a utilization of ferrite sludge were also proposed in this paper.
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