A novel technology for the simultaneous removal of NO
x (= NO + NO
2) and SO
x (= SO
2 + SO
3) in the flue gas of a glass manufacturing system is described using a plasma-chemical hybrid process (PCHP). The exhaust gas is produced by combustion of liquefied natural gas and contains both NO
x (189 - 335 ppm) and SO
x (109 - 183 ppm). Lowering the flue gas temperature from more than 200 °C to less than 150 °C is required for effective NO oxidation (80% efficiency) to NO
2 by ozone gas injection. Therefore, a mixture of ozone and water are sprayed by compressed air from the three-fluid spray nozzle into the exhaust duct. The ozone gas is prepared using an electrical discharge-induced nonthermal plasma apparatus. In addition, almost all of the SO
2 is absorbed by a NaOH absorbent resulting in the generation of Na
2SO
3. Furthermore, reduction of the water-soluble NO
2 by Na
2SO
3 to N
2 affords Na
2SO
4, which can be reused as glass material. The highest removal efficiency of 39% for NO
x is obtained when the NO
x concentration is reduced from 315 ppm to 193 ppm (O
3/NO = 0.32). This simultaneous de-SO
x and de-NO
x technology by PCHP is highly effective and promising for exhaust gas treatment for a glass manufacturing system.
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