Nippon kagaku zassi

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ISSN-L : 0369-5387

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Volume 89, Issue 1

Displaying 1-29 of 29 articles from this issue

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Photo-ionization and Photolysis of Aromatic Molecules in Solutions

Hiroshi TSUBOMURA

1968 Volume 89 Issue 1 Pages 1-13
Published: January 10, 1968
Released on J-STAGE: May 30, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.1

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H. M. O. Treatment of the Effects of 6-Substituents on the Acetolyses of 9-Benzorbornenyl Brosylates

Hiroshi TANIDA, Tadahiko TSUSHIMA

1968 Volume 89 Issue 1 Pages 14-18
Published: January 10, 1968
Released on J-STAGE: May 30, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.14

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Normal Vibrations and Assignments of Infrared Spectra of Propane and Its Deuterium Derivatives

Teiichiro OGAWA, Jizaemon HARA, Kozo HIROTA

1968 Volume 89 Issue 1 Pages 19-22
Published: January 10, 1968
Released on J-STAGE: May 30, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.19

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The Intensity Calculation for Infrared Spectra of Vinyl Group of the Alkenes

Seiichiro HIGUCHI, Shigeyuki TANAKA, Hitoshi KAMADA

1968 Volume 89 Issue 1 Pages 22-24
Published: January 10, 1968
Released on J-STAGE: May 30, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.22

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Absorption Spectra of 1: 1 Metal Complexes of Phenolazopyrazolone Derivatives

Hitoshi KAMADA, Shozo TODA, Hiroshi KOBAYASHI, Motonobu ITO

1968 Volume 89 Issue 1 Pages 25-28
Published: January 10, 1968
Released on J-STAGE: May 30, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.25

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Absorption Spectra of 1: 2 Chromium(III) Complexes of Phenolazopyrazolone Derivatives

Shozo TODA, Hiroshi KOBAYASH, Motonobu ITO, Hitoshi KAMADA

1968 Volume 89 Issue 1 Pages 29-32
Published: January 10, 1968
Released on J-STAGE: May 30, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.29

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The Method of Determination of the Thermal Diffusion Constant

Masahiro IMAOKAM, Masao YAMAMOTO, Kozo HIROTA

1968 Volume 89 Issue 1 Pages 32-34
Published: January 10, 1968
Released on J-STAGE: May 30, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.32

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The Decomposition of Formic Acid on the Iron-Chromium Alloy

Ikuya MATSUURA, Chiyoko SUZUKI

1968 Volume 89 Issue 1 Pages 35-37
Published: January 10, 1968
Released on J-STAGE: May 30, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.35

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Dynamic Properties of Plasticized Polyvinyl Chloride

Kunio NAKAMURA, Tsurutaro NAKAGAWA

1968 Volume 89 Issue 1 Pages 38-41
Published: January 10, 1968
Released on J-STAGE: May 30, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.38

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Effects of Addends on Viscosily of Acetone Solutions of Polyvinyl Acetates and Its Partly Saponified Products

Yasuyoshi SAKAGUCHI, Inako MESHINO, Tatsuko SAWADA, Katsuyuki TAMAKI

1968 Volume 89 Issue 1 Pages 42-44
Published: January 10, 1968
Released on J-STAGE: May 30, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.42

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The Charge-transfer Band of Iron(II) Complexes with 1, 2Diketone Dioximes and Pyridine

Chuya MATSUMOTO, Yukio YAMANO, Koichiro SHINRA

1968 Volume 89 Issue 1 Pages 44-48
Published: January 10, 1968
Released on J-STAGE: May 30, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.44

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Determination of Mononuclear Aluminum Complex Ions in the Presence of Large Amount of Polynuclear Aluminum Species

Katsumi GOTO, Takao YOTSUYANAGI

1968 Volume 89 Issue 1 Pages 49-53
Published: January 10, 1968
Released on J-STAGE: May 30, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.49

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Stability Constant of Iron(III)-5-Hydroxychromone Complex studies on the Hydroxyl Derivatives of Chromone as Analytical Reagents. IV.

Akira MURATAT, Takushi ITO, Tetsuo SUZUKI

1968 Volume 89 Issue 1 Pages 54-57
Published: January 10, 1968
Released on J-STAGE: May 30, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.54

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Polarography of Manganeses in Mannitol-Potassium Hydroxide Solution

Toshioki AMEMIYA, Hiroshi HIRATA

1968 Volume 89 Issue 1 Pages 58-62
Published: January 10, 1968
Released on J-STAGE: May 30, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.58

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The Isolation and Characteristics of Jasminin, a Bitter Component from the Leaves of Jasminum primulinum HEMSL.

Takashi KUBOTA, Nobutaka ICHIKAWA, Tadao KAMIKAWA

1968 Volume 89 Issue 1 Pages 62-65
Published: January 10, 1968
Released on J-STAGE: September 02, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.62

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A new bitter component named jasminin from the leaves of Jasminum primulinum HEMSL. has been isolated. The bitter component is a crystalline glucoside, C₂₆H₃₈0₁₂, the functional groups of which have been characterized.

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Telomerization of Isoprene with Formic Acid

Juntaro TANAKA, Takao KATAGIRI, Toru TAKESHITA

1968 Volume 89 Issue 1 Pages 65-69
Published: January 10, 1968
Released on J-STAGE: September 02, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.65

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The telomerizations of isoprene with carboxylic acids were studied in detail. The results obtained from formic acid as the telogen and perchloric acid as the catalyst were reported.
It was found that these reactions were controlled b y the amount of water to produce the monoterpene compounds.
The telomers obtained were hydrolyzed to the alcohols and were identified by means of GLC, TLC and IR. The main products were confirmed as the 1, 4-coupling compounds of isoprene, i. e., geraniol and α-terpineol.
This telornerization preceeded accompanying oligomreization and the small amount of terpene hydrocarbons were obtained. The telomers and the hydrocarbons were separated by means of liquid chromatography. The hydrocarbon fractions may contain monocyclic terpenoids, i. e. dipentene and terpinolene.

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Syntheses and Ring Closure Reactions of 1-Aryl-4-acylsemicarbazides

Otohiko TSUGE, Tadashi ITOH, Shuji KANEMASA

1968 Volume 89 Issue 1 Pages 69-74
Published: January 10, 1968
Released on J-STAGE: September 02, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.69

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Benzoyl, phenylacetyl, 2-furoyl, 2-thenoyl, is ophthaloyl and terephthaloyl isocyanates reacted with phenylhydrazine, giving the corresponding 1-phenyl-4-acylsemicarbazides quantitatively. The treatment of the above semicarbazides with aqueous hydrochloric acid or aqueous potassium hydroxide afforded the corresponding 3-hydroxy-1, 2, 4-triazoles in good yields. On the other hand, the thermal ring closure of the semicarbazides gave quantitatively the corresponding 1H-2, 3-dihydro-1, 2, 4-triazol-3-ones.
In the thermal ring closure of 1-(p-substituted phenyl)-4benzoylsemicarbazides which were obtained fr the reaction-of benzoyl isocyanate with p-substituted phenylhydrazines, however, the corresponding 3-hydroxy-1, 2, 4-triazole or 1H2, 3-dihydro-1, 2, 4-triazol-3-one, or both were formed the relative amount of the triazoles depending on the nature of the substituent. The reaction course of the thermal ring closure was briefly discussed.

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Decarbonylation of Diphenylketene by Organometallic Compounds

Pangbu HONG, Kenkichi SONOGASHIRA, Nobue HAGIHARA

1968 Volume 89 Issue 1 Pages 74-77
Published: January 10, 1968
Released on J-STAGE: May 30, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.74

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Reactions of Polysubstituted Benzyl Nitrates

Kazuhiro MARUYAMA, Kiyomi NAKAMURA, Hitomi SUZUKI

1968 Volume 89 Issue 1 Pages 78-82
Published: January 10, 1968
Released on J-STAGE: May 30, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.78

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Syntheses of Some Sulfonium and Selenonium Compounds Containing a Phenacyl Group

Tsugio HASHIMOTO, Hisao KITANO, Kenichi FUKUI

1968 Volume 89 Issue 1 Pages 83-87
Published: January 10, 1968
Released on J-STAGE: May 30, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.83

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Halomethylation of β-Pinene Initiated by Pentacyanocobaltate

Kimio TARAMA, Takuzo FUNABIKI

1968 Volume 89 Issue 1 Pages 88-92
Published: January 10, 1968
Released on J-STAGE: May 30, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.88

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Isomerization of 3, 4-Dichloro-l-butene with Palladium Catalysts

Akio OSHIMA

1968 Volume 89 Issue 1 Pages 92-93
Published: January 10, 1968
Released on J-STAGE: May 30, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.92

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The Nitration of Veratraldehyde Dimer and Acetylvanillin Dimer

Yoshimori OMOTE, Yoshimori FUJINUMA, Noboru SUGIYAMA

1968 Volume 89 Issue 1 Pages 94-95
Published: January 10, 1968
Released on J-STAGE: May 30, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.94

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The Eicosatrienoic Acid in the Seed Oil of Torreya nucifera

Yoshito KOYAMA, Yasuji OKADA, Yoshiyuki TOYAMA

1968 Volume 89 Issue 1 Pages 95-97
Published: January 10, 1968
Released on J-STAGE: May 30, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.95

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Catalytic Hydrogenolysis of 7, 7-Dibromonorcarane

Koji ISOGAI, Seiichiro KONDO

1968 Volume 89 Issue 1 Pages 97-98
Published: January 10, 1968
Released on J-STAGE: May 30, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.97

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The Reaction between Phenols and α-Phenylcinnamic Acid in the Presence of Polyphosphoric Acid

Noboru HASEBE, Hidemasa OMURA

1968 Volume 89 Issue 1 Pages 99-100
Published: January 10, 1968
Released on J-STAGE: May 30, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.99

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Acylation with 2-Acyloxypyridines and 2-Acylthiopyridines

Yoshio UENO, Shiro ASAKAWA, Eiji IMOTO

1968 Volume 89 Issue 1 Pages 101-102
Published: January 10, 1968
Released on J-STAGE: May 30, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.101

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The Crystal Structure of Sulfatopentamminecobalt(III) Hydrogensulfate Dihydrate, [CoSO₄(NH₃)₅] HSO₄. 2H₂0

Yoshihiko KUSHI, Hajime TSUNO, Hisao KUROYA

1968 Volume 89 Issue 1 Pages 102-103
Published: January 10, 1968
Released on J-STAGE: May 30, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.102

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Abstracts

1968 Volume 89 Issue 1 Pages A1-A6
Published: January 10, 1968
Released on J-STAGE: May 30, 2011

DOIhttps://doi.org/10.1246/nikkashi1948.89.A1

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