In this study, we investigated the influence of particle concentration on the magnetic solution deposition method, which forms thin films by effectively sedimenting magnetic nanoparticles in a liquid. We varied the area fraction and investigated the thin film formation conditions in detail through Brownian dynamics simulations. Specifically, we analyzed the effects of the magnetic field strength, magnitude of magnetic interactions between particles, particle mass density, and liquid temperature on the sedimentation behavior. In particular, we focused on the area fraction, which was previously set to 0.227, and conducted a comparative study using six different values, with the upper limit set to 0.403. We statistically analyzed 60,000 simulation cases to identify the conditions under which the desired thin film could be formed. The results showed that as the strength of the applied magnetic field increased, the magnetic moments of the particles became more closely aligned with the field direction, thereby reducing the likelihood of cluster formation and enhancing the possibility of obtaining the desired thin film. However, when the area fraction increased, the interparticle distance decreased, and even the particles aligned in the direction of the magnetic field tended to form clusters, making it more difficult to obtain the desired film. When the area fraction exceeded 0.227, the number of conditions under which a thin film could be formed decreased sharply; at 0.403, film formation became completely impossible. These findings indicate that the upper threshold of the area fraction for successful magnetic solution deposition is likely to be within 0.251–0.403.
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