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  • 連 勇太朗
    日本建築学会計画系論文集
    2023年 88 巻 814 号 3235-3246
    発行日: 2023/12/01
    公開日: 2023/12/01
    ジャーナル フリー

    This study aims to develop a theoretical foundation for considering architecture as knowledge commons. The findings of commons research were applied by setting research questions on 1) how architecture can be considered as knowledge commons and 2) what kind of architecture can be defined as knowledge commons. The achievement of this study is to present an analytical framework called the AKC (Architecture Knowledge Commons) framework, which is an application of the IAD framework, the core methodology of commons research, to architecture, and to identify the theoretical conditions for considering architecture as knowledge commons.

  • Odawara Osamu, Fujita Osamu
    日本マイクログラビティ応用学会誌
    2007年 24 巻 3 号 205-
    発行日: 2007年
    公開日: 2021/01/21
    ジャーナル オープンアクセス
  • Olivier Birmann, 吉本 素子
    関西フランス語フランス文学
    2000年 6 巻 82-84
    発行日: 2000/03/31
    公開日: 2017/07/14
    ジャーナル フリー
  • Tzee-
    Char
    KUO
    Journal of the Mathematical Society of Japan
    1980年 32 巻 4 号 605-614
    発行日: 1980年
    公開日: 2006/10/20
    ジャーナル フリー
  • Sin-Myoung Kang, Sanghoon Joo, Dong-Joon Min, Il-Ock Lee
    ISIJ International
    1996年 36 巻 2 号 156-163
    発行日: 1996/02/15
    公開日: 2007/05/31
    ジャーナル フリー
    The present study has been carried out to investigate the simultaneous behavior of combustion of 'pulverized coal
    char
    ' (described as '
    char
    ' afterwards in this paper), and of reduction of fine iron ore using a laboratory scale tube furnace.
    Experimental results show that apparent combustion rate of
    char
    is not affected by the ore/
    char
    mole ratio simultaneously injected. The reaction rate constant of
    char
    was not changed with changing wustite/
    char
    injection ratio. On the other hand, the rate constant of
    char
    increased proportionally with an increase of hematite/
    char
    injection ratio. This implies that hematite behaves as an effective oxygen source for
    char
    combustion.
    The main reduction mechanism of fine wustite injected is found to be the direct reduction between molten wustite and unburnt carbon. Similarly, for the case of fine hematites, the direct reduction between molten magnetite thermally decomposed from hematite and solid carbon entrained into the droplet is the main reduction mechanism.
    It was observed that the reduction degree of fine iron oxides mainly depends on the specific combustion heat (kJ/g-ore) which is defined as the ratio of combustion heat of
    char
    to the feeding rate of fine iron oxide.
  • 佐野安船渠株式会社
    関西造船協会誌
    1981年 183 巻
    発行日: 1981/12/30
    公開日: 2018/03/30
    会議録・要旨集 フリー
  • Allan K. Chambers
    International Journal of the Society of Materials Engineering for Resources
    1999年 7 巻 2 号 267-272
    発行日: 1999年
    公開日: 2010/10/21
    ジャーナル フリー
    Briquettes for heating or cooking are often made by pressing a blend of various chars. Desirable briquette properties include ease of ignition, minimal odors, high heat and long burning time. Lignite
    char
    contributes high heat and long burning but is often mixed with wood
    char
    to improve the ease of ignition. A thermogravimetric procedure was developed to measure the ignition proper ties of various lignite and wood
    char
    samples. Chars were collected at several points in the charring process or produced in the laboratory. Charring temper ature, time and length of aging of the
    char
    in air were important factors in the final
    char
    ignition properties.
    Char
    ignition temperature correlated well with the hydrogen content of the
    char
    .
  • *Qianshi SONG, Xiaohan Wang, Takaoka Masaki
    廃棄物資源循環学会研究発表会講演集
    2022年 33 巻 IC-6-O
    発行日: 2022年
    公開日: 2022/11/30
    会議録・要旨集 フリー

    In this study, a theoretical model was constructed for the

    char
    gasification process, including
    char
    pore structure sub-model, inorganic element catalytic/inhibitory index factor sub-model and structure function sub-model, combined with the simple gas-solid collision theory to predict the
    char
    gasification reaction rate. In the experimental part, six typical biomass samples were selected and placed on thermogravimetric analyzer to test the
    char
    gasification rate. The model calculated values were in good agreement with the experimental results, indicating the reliability of the model.

  • Ryota Murai, Minoru Asanuma, Michitaka Sato, Takanori Inoguchi, Kaneo Terada
    ISIJ International
    2015年 55 巻 3 号 528-535
    発行日: 2015/03/15
    公開日: 2015/04/17
    ジャーナル オープンアクセス HTML
    Injection of plastics into blast furnaces as an alternative reducing agent has been carried out for the purpose of mitigation of carbon dioxide emissions. Several studies on the pyrolysis of plastic particles have been reported, however flow behavior of plastic particles or unburnt
    char
    in actual blast furnace is not clear.
    In this study, hotmodel experiments and thermogravimetry analysis were conducted for the modeling of gasification and combustion behavior of plastic particles, then flow behavior of plastic particle and unburnt
    char
    in a blast furnace was calculated by numerical simulation. According to the observation results of combustion experiment, volatile matter of plastics seems to be evolved at the surface of the particles. Regarding reaction of
    char
    derived from plastics, thermogravimetry analysis showed that rate of gasification of unburnt
    char
    depended on the rate of heating. Gasification rate in the case of rapid heating condition tended to increase.
    As the results of numerical simulations, initial diameter of plastics and
    char
    diameter determined the flow behavior in the blast furnace. When relatively small plastic was injected or diameter of unburnt
    char
    was small, unburnt
    char
    went upward along with gas flow and most of it might be consumed at the cohesive zone. On the other hand, when relatively coarse plastics was injected and diameter of unburnt
    char
    was relatively coarse, it was suggested that unburnt
    char
    accumulated around the deadman.
    Therefore, it is considered that fine plastics injection is desirable for the stable operation of blast furnace.
  • Takazo Kawaguchi, Masaki Hara
    ISIJ International
    2013年 53 巻 9 号 1599-1606
    発行日: 2013/09/15
    公開日: 2013/10/03
    ジャーナル オープンアクセス HTML
    Decrease of carbon dioxide emission is a serious subject in the steel works. Utilization of biomass as a carbon-neutral agent is an attractive one for iron ore sintering. Sinter pot tests were carried out with using raw biomass and biomass carbonized
    char
    . It is not good on yield and exhaust gas that raw biomass is used directly as carbon material for iron ore sintering. While, it is good on the productivity and the exhaust gas (NOx, SOx, dust, dioxins) that biomass carbonized
    char
    is used as carbon material. With using biomass
    char
    for the sintering, it is necessary to optimize operation (size control and moisture control of the biomass
    char
    ), because combustion rate of the biomass
    char
    is too high. Biomass carbonized
    char
    is evaluated on sinter yield as similar as anthracite or coke. The biomass
    char
    is effective to decrease CO2, NOx, SOx, dust etc. emission in sinter exhaust gas.
  • Alya Naili Rozhan, Mohd Hanafi Ani, Hamzah Mohd Salleh, Tomohiro Akiyama, Hadi Purwanto
    ISIJ International
    2015年 55 巻 2 号 436-440
    発行日: 2015/02/15
    公開日: 2015/02/20
    ジャーナル オープンアクセス HTML
    This paper presents a technology to utilize bio-
    char
    and bio-tar from the pyrolysis of oil palm empty fruit bunch, EFB. In this study, tar vapor from pyrolysis of EFB was infiltrated within porous bio-
    char
    and carbon deposition occurred on the pore surface by chemical vapor infiltration process. For preparation, EFB particles were made into pellets. In the first part of experiments, porous bio-
    char
    pellets were produced by slowly heating the EFB pellets in a tube furnace in argon atmosphere to terminal temperatures of 500–800°C. In the second part, the porous bio-
    char
    pellets were used as precursor for tar decomposition process to deposit carbon within the bio-
    char
    pores. Tar vapor was obtained from the pyrolysis of EFB at 400–500°C at a fast heating rate for tar decomposition to occur. The purpose of this research is to investigate the amount of carbon deposited within bio-
    char
    by this tar carbonization process as compared to carbon contents of metallurgical coke. We showed how EFB bio-
    char
    was used as the tar filter and in the process to produce carbon-infiltrated bio-
    char
    , a useful renewable energy source for ironmaking process.
  • 丸岡 大佑, 中村 拓正, 村上 太一, 葛西 栄輝
    鉄と鋼
    2016年 102 巻 12 号 730-735
    発行日: 2016年
    公開日: 2016/11/30
    ジャーナル オープンアクセス HTML

    Carbonization behavior of biomass in the rapid carbonization/pulverized process using heat storage materials was experimentally examined. Biomass samples were charged into a rotary kiln-type electric furnace with stainless balls. Obtained biomass chars were evaluated by means of gasification test in CO2 atmosphere using a thermal gravimetry. The

    char
    was classified into two type, “fine” and “coarse”, by particle size.

    “Coarse”

    char
    contracted with increasing holding temperature. Crashing of biomass
    char
    was observed at the holding temperatures over 600°C and fine
    char
    was formed. Melted structure was observed on the surface of “coarse”
    char
    indicating rapid heating. Yields of the total
    char
    are decreased with increasing holding temperature due to vaporization of volatile matters like tar. On the other hand, the yield of “fine”
    char
    is increased with increasing rotation speed when carbonization reaction sufficiently proceeded.

    The

    char
    obtained by the present carbonization experiment at between 600 and 800°C for 10 min showed similar gasification property with CO2 to that prepared by normal carbonization at 800°C for 1 h.

  • 村井 亮太, 浅沼 稔, 佐藤 道貴, 井ノ口 孝憲, 寺田 周雄
    鉄と鋼
    2016年 102 巻 8 号 434-442
    発行日: 2016年
    公開日: 2016/07/31
    [早期公開] 公開日: 2016/05/20
    ジャーナル オープンアクセス HTML
    Injection of plastics into blast furnaces as an alternative reducing agent has been carried out for the purpose of mitigation of carbon dioxide emissions. Several studies on the pyrolysis of plastic particles have been reported, however flow behavior of plastic particles or unburnt
    char
    in actual blast furnace is not clear.
    In this study, hotmodel experiments and thermogravimetry analysis were conducted for the modeling of gasification behavior of plastic particles, then flow behavior of plastic particle and unburnt
    char
    in a blast furnace was calculated by numerical simulation. According to the observation results of gasification experiment, volatile matter of plastics seems to be evolved at the surface of the particles. Regarding reaction of
    char
    derived from plastics, thermogravimetry analysis showed that rate of gasification of unburnt
    char
    depended on the rate of heating. Gasification rate in the case of rapid heating condition tended to increase.
    As the results of numerical simulations, initial diameter of plastics and
    char
    diameter determined the flow behavior in the blast furnace. When relatively small plastic was injected or diameter of unburnt
    char
    was small, unburnt
    char
    went upward along with gas flow and most of it might be consumed at the cohesive zone. On the other hand, when relatively coarse plastics was injected and diameter of unburnt
    char
    was relatively coarse, it was suggested that unburnt
    char
    accumulated around the deadman.
    Therefore, it is considered that fine plastics injection is desirable for the stable operation of blast furnace.
  • 佐藤 道貴, 深田 喜代志, 有山 達郎, 板垣 省三, 村井 亮太
    鉄と鋼
    2001年 87 巻 5 号 365-372
    発行日: 2001/05/01
    公開日: 2009/06/19
    ジャーナル フリー
    To clarify the gasification and consumption behavior of unburnt
    char
    ascending in the coke packed bed in the lower part of the blast furnace,
    char
    reaction-consumption model has been newly developed considering the average residence time and co-gasification with coke particles. The chemical reaction rate constant has been determined based on the high temperature experiments on the
    char
    injection into the coke packed bed.
    From the analyses using this model, the following results were obtained.
    ( 1 ) The mean ascending velocity of
    char
    particles with the diameter of 20 μm was approximately 0.3 m/s, and it was smaller than the actual gas velocity by one order of magnitude, suggesting the
    char
    particles had fairly long residence time in the blast furnace.
    ( 2 ) The consumption rate of
    char
    became lower with the increase in the solid-gas loading ratio. This was considered to be caused by the higher ascending velocity which resulted from the successive renewal of stagnant particles in the packed bed by supplied
    char
    particles.
    ( 3 ) According to the examination of
    char
    consumption behavior along the blast furnace height,
    char
    discharge rate from the top of the thermal reserve zone could be reduced considerably by decreasing
    char
    exhaust rate from the raceway. This phenomenon resulted from the increase in the consumption rate throughout the height, due to the decrease in the solid-gas loading ratio. Therefore, to suppress the
    char
    exhaustion from the top, it was necessary to improve the combustion efficiency in the raceway at higher injection rate of pulverized coal.
  • Kiyohiro Ishikawa, Yasushi Sekine, Eiichi Kikuchi, Masahiko Matsukata
    アジア・太平洋化学工学会議発表論文要旨集
    2004年 2004 巻 1P-02-034
    発行日: 2004年
    公開日: 2005/04/08
    会議録・要旨集 フリー
    The purpose of this study is to clarify the relationship among the reactivity of coal
    char
    , the carbonaceous structural change, and the ash behavior. The steam gasification of various coal
    char
    was carried out in a fixed-bed reactor. After the gasification, the reacted
    char
    was analyzed by LRS (Laser Raman Spectroscope), and SEM/EDX (Scanning Electron Microscope, Energy Dispersive X-ray Spectroscopy). In order to evaluate the progress of carbonaceous graphitization, we observed ID/IV ratio that was one of the Raman parameters. As a result, graphitization of coal
    char
    was equally observed under every condition as the increasing of conversion rate. So we estimated that the progress of graphitization would be caused with following reason. Disordered carbon structure, whose reactivity was higher, had been gasified alternatively, consequently the ratio of carbon that had graphitic structure increased relatively.Then in order to clarify the ash behavior affecting the
    char
    reactivity, characterizations of each
    char
    was carried out using SEM/EDX. From the results of observing SEM image and EDX-mapping, we found the different behavior of elements and novel parallel analysis between EDX-mapping and LRS-mapping was very effective for the comprehensive evaluation of ash behavior and carbonaceous structure. As the gasification reaction, the reactivity of
    char
    was partially decreased, because the surface of carbon had been covered with certain elements such as Si, and reaction gas could not contact with the carbon.
  • 川上 正博, 大藪 貴之, 水谷 行隆, 竹中 俊英, 横山 誠二
    鉄と鋼
    2003年 89 巻 5 号 581-586
    発行日: 2003/05/01
    公開日: 2009/05/29
    ジャーナル フリー
    The reaction rates of Bintyo
    char
    , Bamboo
    char
    , activated carbon, coke, graphite and glassy carbon with pure CO2 have been obtained by thermo gravimetric method. After the reaction, N2 was introduced to the reaction tube to obtain the amount of adsorbed CO on the active reaction sites. The specific surface area after the reaction was measured by BET method. The results are summarized as follows:
    The reaction rate per unit mass were in the order of Bintyo
    char
    _??_Bamboo
    char
    _??_activated carbon>graphite_??_coke>glassy carbon. The difference between the maximum and minimum were two orders of magnitude. The activation energy was 180 to 220 kJ/mol. The reaction rate per unit area of graphite, however, was an order of magnitude higher than those of Bintyo
    char
    and Bamboo
    char
    . The estimated amount of adsorbed CO was positively correlated to the reaction rate. The reaction rate constant which is independent from surface area was obtained using the reaction rate and the amount of CO adsorption, respectively per unit area. They are ranged in the order of 10-4 to 10-3 1/s. The differences among Bintyo
    char
    , Bamboo
    char
    and graphite became smaller. The enthalpy of CO adsorption was estimated as about 230 kJ/mol for Bintyo
    char
    and Bamboo
    char
    , and about 280 kJ/mol for graphite.
  • Mamoru KAMISHITA, Takeshi OGASAWARA, Hidetaro TANIHARA
    Transactions of the Iron and Steel Institute of Japan
    1982年 22 巻 9 号 715-726
    発行日: 1982年
    公開日: 2006/09/08
    ジャーナル フリー
    In order to find its feasibility as blast furnace coke feedstock, non-metallurgical coal was compared with metallurgical coal in terms of reactivity and degradation during CO2 gasification reaction, with emphasis on the difference between the pore structure of coke and that of
    char
    . The following results were obtained:
    (1) The higher reactivity of non-metallurgical coal
    char
    is due to the fact that their coal rank is lower.
    (2) Though the pore structure of metallurgical coke is composed mainly of macropores, pore walls of
    char
    are either abundant in micropores when the rank is low, or practically nil in any size when the rank is relatively high.
    (3) Open macropores characterize the pore structure of coke, while
    char
    has a considerable number of closed pores.
    (4) The deterioration of the structural strength of coke becomes greater than that of
    char
    as gasification reaction proceeds.
  • Liming Lu, Veena Sahajwalla, Chunhau Kong, Alex Mclean
    ISIJ International
    2002年 42 巻 8 号 816-825
    発行日: 2002/08/15
    公開日: 2007/05/31
    ジャーナル フリー
    Using a drop tube furnace,
    char
    samples were prepared from coals of different ranks, under conditions similar to those prevailing during pulverized coal injection into the blast furnace. The chemical structure of resultant chars was determined by quantitative X-ray diffraction analysis (QXRDA) and high-resolution transmission electron microscopy (HRTEM), and investigated as a function of pyrolysis temperature, heating rate and coal type. Among the parameters examined, pyrolysis temperature was the key factor influencing
    char
    chemical structure.
    Char
    obtained at higher temperature is generally more ordered, with the distinctive peaks becoming sharper and the background intensity becoming lower. Heating rate is another important factor affecting
    char
    chemical structure.
    Char
    is more ordered at lower heating rate due to the longer residence time. Although considerable differences were still observed in the chemical structure of chars prepared from coals of different ranks, it is clear that such differences are reduced after coal pyrolysis.
    Char
    structural evolution during post-pyrolysis and combustion was also investigated. The importance and potential applications of this work to the blast furnace PCI operation have been outlined.
  • Takuya Yamashita, Yoshio Morozumi, Hideyuki Aoki, Takatoshi Miura
    アジア・太平洋化学工学会議発表論文要旨集
    2004年 2004 巻 3P-13-005
    発行日: 2004年
    公開日: 2005/04/08
    会議録・要旨集 フリー
    A
    char
    particle gasification model applying the discrete approach has been developed to predict the effect of the
    char
    particle structure (size, porosity and shape) and the reaction temperature on the reaction behavior. In this model, it was assumed that the shape of a
    char
    particle before the reaction was a three-dimensional cube. A large number of small lattices arranged randomly in the cube and were classified into
    char
    , ash and macropore depending on the
    char
    's proximate analysis data. In the
    char
    reaction process, one-dimensional steady state diffusion of CO2 was considered in the cylinders. It was assumed that CO2 diffused through a large number of the cylinders, which represented micropores inside the
    char
    particle and reacted to the wall of the cylinders. The dependence of the reaction rate on the temperature was analyzed by changing the size, porosity and shape. It is suggested that the pore diffusion behavior of CO2 is influenced by the particle structure change. This is because the reaction rate is determined by the relationship between the chemical reaction rate and the diffusion rate. Therefore, CO2 diffusion distance influenced by the particle size, porosity or shape, which is one of the major factors to determine the diffusion rate, remarkably contributes to control the transition temperature between chemical reaction rate controlling regime and pore diffusion rate controlling one. The uniform and peripheral reaction in the particle occurred depending on the reaction temperature. Furthermore, the reaction also occurred on the internal void surface of the particle at the high porosity, while the reaction only occurred on the external surface of the particle at the low porosity. The reaction temperature and porosity influenced the reaction position in the particle, so that the fragmentation behavior was different owing to the porosity and the reacting conditions.
  • Rajender Gupta, Lianguang Tang, Changdong Sheng, Terry Wall, Yoshihiko Endou, Takashi Kiga, Graham O'Brien
    Proceedings of the International Conference on Power Engineering : ICOPE
    2003年 2003.3 巻
    発行日: 2003年
    公開日: 2017/06/19
    会議録・要旨集 フリー
    The paper presents the on-going research in accounting for heterogeneous nature of organic matter in pulverised coal. This is achieved by using the information from automated reflectogram technique developed at CSIRO Australia. The technique is seen as providing opportunities for characterizing coal in a way which, for the first time, will allow the heterogeneous nature of coal to be related to reactivity, ash formed and fine ash generation. All these aspects of coal utilization are related with
    char
    character. The aim of the research is, therefore, to correlate the
    char
    character to the reflectance of an individual coal particle. The coal is considered as a mixture of particles of different character in terms of chemical and physical properties. In the present work, the reflectance is considered as the main characterizing parameter for the organic matter in coal. All the bulk properties of coal or
    char
    can be obtained from the summation of the properties of individual particles. For example, each individual coal particle devolatilises to a different extent resulting in a distinct
    char
    particle. The properties of these
    char
    particles vary monotonously with reflectance. A correlation was obtained for volatile matter as a function of reflectance in such a way that the volatile mater could be obtained from the reflectogram analysis using this relationship. This approach is extended to
    char
    character.
    Char
    was produced from several coal samples and maceral concentrates in a drop tube furnace at 1400C. The porosity and average thickness of the
    char
    particles were estimated from image analysis. Coal particles with low reflectance are expected to result in porous and thin-shelled
    char
    particles. The was observed qualitatively in these
    char
    samples. A relationship between reflectivity/reflectance of coal particles and the porosity of the resulting
    char
    particles is obtained from regression analysis. This relationship is very important in modeling combustion of
    char
    particles and ash formation. The effect of
    char
    morphology on burnout is demonstrate using CBK7,a combustion model. The implication on ash formation is also discussed.
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