Journal of The Adhesion Society of Japan
Online ISSN : 2187-4816
Print ISSN : 0916-4812
ISSN-L : 0916-4812
Original Paper
Vibrational Spectroscopic Studies on Wood and Wood-Based Materials(V) Infrared Microspectroscopic Investigation for Penetration Behavior of Isocyanate Adhesives at Wood-Dowel Joints
Shige YAMAUCHIYuich MATSUKIShosuke OHTATatsuya OKUNOYasuo TAMURA
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JOURNAL FREE ACCESS

2000 Volume 36 Issue 7 Pages 250-258

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Abstract
Wood dowel (Acer mono) was joined into wood member (Cryptomeria japonica) by a polymeric MDI(PMDI) or a polyurethane resin , which is an isocyanate adhesive. Infrared microspectrosopicspectra at the joints were 2-dimensionally measured by diffuse reflectance method , and then NCO group was identified due to its asymmetric stretching vibrational band (2270cm⁻¹).Thedistributions of the adhesives (isocyanate compounds) around the joints were displayed by colorscorresponding to the band intensityat 2270cm⁻¹. The color maps exhibited that the PADI excessively penetrates into the wood member in the axial direction because of its low viscosity (ca.0.2 Pa.s) , and indicated that only the fluid components in the polyurethane resin (ca.200 Pa・s) , which are not so large , move from the glue line to the wood member. (Received:December15,1999)
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© 2000 The Adhesion Society of Japan
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