Analytical Sciences
Online ISSN : 1348-2246
Print ISSN : 0910-6340
ISSN-L : 0910-6340
Original Papers
Analysis of Writing Ink Dyestuffs by TLC and FT-IR and Its Application to Forensic Science
Kazuhiro TSUTSUMIKazuya OHGA
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1998 年 14 巻 2 号 p. 269-274

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Black, blue and red writing pens were classified into various groups using the Rf values and color tones of dyestuff bands separated by normal-phase thin-layer chromatography (TLC) of their inks. The classification is effective for the preliminary identification of pens used in crime scenes. A microsampling technique was proposed for the TLC analysis of minute quantities of inks on questioned documents. Furthermore, a combination of reflectance-mode microscope/Fourier transform infrared spectroscopy and the pin-point condensation technique was proved to be useful for the precise discrim-ination of trace amounts of analogous water-soluble dyestuffs on TLC plates.
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© 1998 by The Japan Society for Analytical Chemistry
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