Analytical Sciences
Online ISSN : 1348-2246
Print ISSN : 0910-6340
ISSN-L : 0910-6340
Original Papers
Computational Aspects of Extraction Equilibrium and Distribution Potential of Electrolyte Distributed between Two Liquid Polar Phases
Jirí RAIS
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1998 年 14 巻 2 号 p. 293-297

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It is proved that both “electrochemical” and “chemical” treatments of the equilibrium distribution of electrolytes between two polar solvents are correct, or in other words the use of electrochemical or chemical potentials is interchangeable. This is illustrated by calculation using a recursive iteration program for distribution of Sr2+ by dicarbollide anion in the presence of polyethyleneglycol. Several particular situations are described: the effect of common ion, limiting distribution coefficient and influence of protonized particles on distribution of cations.
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© 1998 by The Japan Society for Analytical Chemistry
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