Analytical Sciences
Online ISSN : 1348-2246
Print ISSN : 0910-6340
ISSN-L : 0910-6340
Original Papers
Speciation Analysis of Arsenic in Traditional Chinese Medicines by Hydride Generation-Atomic Fluorescence Spectrometry
Li-li YANGLi-rong GAODe-qiang ZHANG
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2003 年 19 巻 6 号 p. 897-902

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A method has been described for the determination of arsenic species (arsenite and arsenate) by hydride generation-atomic fluorescence spectrometry (HG-AFS). The experimental conditions that influence the fluorescence intensity and the reduction of arsenic were investigated and optimized, and the influences from foreign ions and their elimination were studied. The detection limit was found to be 79.7 ng L-1. The proposed method was applied to the determination of arsenic species in water leachate of traditional Chinese medicines with a recovery range of 91.1 - 109.5%.

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© 2003 by The Japan Society for Analytical Chemistry
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