Analytical Sciences
Online ISSN : 1348-2246
Print ISSN : 0910-6340
ISSN-L : 0910-6340
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Mechanism of Gold Adsorption by Persimmon Tannin Gel
Akira NAKAJIMAKaoru OHEYoshinari BABATsuyoshi KIJIMA
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2003 Volume 19 Issue 7 Pages 1075-1077

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Abstract
Gold adsorption by persimmon tannin (PT) gel from a solution containing hydrogen tetrachloroaurate(III) was examined. A flow-rate examination in a column system indicated the reduction of Au(III) ion to Au(0). XRD patterns clarified the existence of Au(0) on the gel which adsorbed gold. The gel could also adsorb colloidal Au(0) prepared independently. A model consisting of ligand exchange, Au(III) reduction to Au(0), and resulting Au(0) adsorption by PT gel was presented for the gold adsorption mechanism.
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© 2003 by The Japan Society for Analytical Chemistry
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