Analytical Sciences
Online ISSN : 1348-2246
Print ISSN : 0910-6340
ISSN-L : 0910-6340
Original Papers
One-step Synthesis of Highly Luminescent Nitrogen-doped Carbon Dots for Selective and Sensitive Detection of Mercury(II) Ions and Cellular Imaging
Ying LIUMei LIAOXueling HEXia LIUXingming KOUDan XIAO
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Supplementary material

2015 Volume 31 Issue 10 Pages 971-977

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Abstract
In this paper, nitrogen-doped carbon dots (N-CDs) with high quantum yield (QY) of 40.5% were prepared through a facile and straightforward hydrothermal route. The as-prepared N-CDs exhibited excellent photoluminescence properties, good water-solublity and photostability, negligible cytotoxicity and favourable biocompatibility. Such N-CDs were found to serve as an effective fluorescent sensor for selective and sensitive detection of Hg2+ in a wide linear response concentration range of 0 – 8 μM with a limit of detection (LOD) of 0.087 μM and could be applied to the determination of Hg2+ in environmental water samples. The corresponding mechanisms were discussed in detail. Moreover, another attractive finding was that the N-CDs showed satisfactory performance in bioimaging before and after the addition of Hg2+ in human lung cancer PC14 cells. With excellent sensitivity, selectivity and biocompatibility, such cheap carbonmaterials are potentially suitable for monitoring of Hg2+ in environmental applications and promising for biological applications.
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© 2015 by The Japan Society for Analytical Chemistry
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