Analytical Sciences
Online ISSN : 1348-2246
Print ISSN : 0910-6340
ISSN-L : 0910-6340
Extra-Atomic Relaxation Effect on the Binding Energy of Reference Gold in X-Ray Photoelectron Spectroscopy
Shigemi KOHIKIKazue OKIFumiya KONISHI
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1985 Volume 1 Issue 2 Pages 115-117

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Abstract
The charge shift correction which utilizes the 4f7/2 binding energy (Eb) of evaporated gold as the reference is investigated for BN, InP, SiO2 and Al2O3 substrates. The change in the final-state relaxation process in low coverage region (_??_2 monolayers) produces inaccuracy of as much as 1eV of binding energy, determined by the gold evaporation method. It is possible to use the 4f7/2 binding energy of evaporated gold as an energy reference in X-ray photoelectron spectroscopy in the coverage region above 2 monolayers.
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© The Japan Society for Analytical Chemistry
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