Analytical Sciences
Online ISSN : 1348-2246
Print ISSN : 0910-6340
ISSN-L : 0910-6340
Enhancement Effect of Palladium Addition in the Determination of Selenium in Organic-Matrix Solutions by Electrically Heated Carbon Furnace Atomic Absorption Spectrometry
Ping LIULei WEIKazuko MATSUMOTOKeiichiro FUWA
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1985 年 1 巻 3 号 p. 257-261

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In selenium determination by carbon-furnace atomic absorption spectrometry, organic materials severely decrease selenium sensitivity. In order to remove the severe negative interference due to organic materials, matrix modifications by addition of Pd, Pt, Ni and Rh were compared. Palladium was found to be most effective. Addition of 100μg ml-1 Pd completely removes the negative interference due to up to 1.5% albumin and restores the sensitivity to that of a simple inorganic Se(IV) solution without organic materials.
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© The Japan Society for Analytical Chemistry
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