Analytical Sciences
Online ISSN : 1348-2246
Print ISSN : 0910-6340
ISSN-L : 0910-6340
Kinetic Separation of Cadmium(II) from Zinc(II) with Dithizone by Back-Extraction
Hideyuki ITABASHIYoshikatsu TAKAZAWANorihiro NIIBEHiroshi KAWAMOTO
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1997 年 13 巻 6 号 p. 921-924

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The back-extraction rate of bis(dithizonato)cadmium(II) was measured, and the possibility of the mutual separation of cadmium(II) from zinc(II) with dithizone by back-extraction was considered. It was found that the back-extraction rate of zinc(II) was much lower than that of Cadmium(II), which could be almost back-extracted within 40s of shaking at pH 1.8, though under these conditions zinc(II) was scarcely back-extracted at all. Based on this, the kinetic separation of cadmium(II) from zinc(II) using a back-extraction procedure could be devised.
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© The Japan Society for Analytical Chemistry
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