Analytical Sciences
Online ISSN : 1348-2246
Print ISSN : 0910-6340
ISSN-L : 0910-6340
Pyrolytic Behaviors of Organic Additives for Direct Rubber Analysis by Pyrolysis-GC/MS
Seung Wook KIMGwi Suk HEOGae Ho LEE
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1997 Volume 13 Issue Supplement Pages 257-262

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Abstract
The pyrolysic behaviors of coumarone-indene resin and alkylphenol resorcinol-formaldehyde resin have been studied for the direct component analysis in cured rubber. The pyrolysis-pathways based upon main primary degradation products have been proposed to identify the mass spectrum of pyrolyzates. From the coumarone-indene resin, the indene, coumarone, coumarone-indene (m/z 234), and indene-indene (m/z 232) were observed as the characteristic monomeric and/or sequential pyrolyzates. Resorcinol and t-octylphenol were observed as main pyrolyzates in alkylphenol resorcinol-formaldehyde. Upon these pyrolysic behavior, it would be readily available to identify these oligomeric resins in a cured rubber.
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© The Japan Society for Analytical Chemistry
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