Analytical Sciences
Online ISSN : 1348-2246
Print ISSN : 0910-6340
ISSN-L : 0910-6340
Determination of Reactive and Total Iron in Fresh Waters Filtered with Various Membranes
Susumu OSAKIYasuhiro KUROKINaoshi MANNENYoshimasa TAKASHIMA
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1986 年 2 巻 1 号 p. 57-60

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The reactive iron contents of fresh water samples filtered with membrane and ultrafiltration filters were determined by an isotope dilution method using the solvent extraction of 4, 7-diphenyl-1, 10-phenanthroline(bathophenanthroline)- Fe complex into 3-methyl-1-butanol (isoamyl alcohol). The total iron contents were determined in the same manner after digestion and dissolution with perchloric acid and hydrofluoric acid. Only small amounts of reactive iron were found in water samples collected upstream, at the reservoir and underground. It is noted that almost all iron in these water samples is present as stable forms. Considerable amounts of reactive iron were found in downstream water, especially as surface species on particulates larger than 5μm.
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© The Japan Society for Analytical Chemistry
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