DETERMINATION OF TRIBUTYLTIN AND TRIPHENYLTIN COMPOUNDS IN ENVIRONMENTAL AND INDUSTRIAL WASTE WATERS BY GAS CHROMATOGRAPHY

YUKIKAZU HATTORI; HITOSHI YAMAMOTO; KANJI NAGAI; KAZUYO NONAKA; HIROKAZU HASHIMOTO; SATOSHI NAKAMURA; MASAO NAKAMOTO; HIROAKI SHIRAISHI; MASATOSHI MORITA

doi:10.2116/analsci.7.Supple_1081

YUKIKAZU HATTORI, HITOSHI YAMAMOTO, KANJI NAGAI, KAZUYO NONAKA, HIROKAZU HASHIMOTO, SATOSHI NAKAMURA, MASAO NAKAMOTO, HIROAKI SHIRAISHI, MASATOSHI MORITA

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YUKIKAZU HATTORI
Environmental Pollution Control Center, Osaka Prefevtural Government
HITOSHI YAMAMOTO
Environmental Pollution Control Center, Osaka Prefevtural Government
KANJI NAGAI
Environmental Pollution Control Center, Osaka Prefevtural Government
KAZUYO NONAKA
Environmental Pollution Control Center, Osaka Prefevtural Government
HIROKAZU HASHIMOTO
Environmental Pollution Control Center, Osaka Prefevtural Government
SATOSHI NAKAMURA
Environmental Pollution Control Center, Osaka Prefevtural Government
MASAO NAKAMOTO
Environmental Pollution Control Center, Osaka Prefevtural Government
HIROAKI SHIRAISHI
National Institute for Environmental Studies
MASATOSHI MORITA
National Institute for Environmental Studies

Keywords: tributyltin and triphenyltin compounds, tripentyltin as surrogate compound, capillary GC-flame photometric detection, propylation with propylmagnesium bromide

JOURNAL FREE ACCESS

1991 Volume 7 Issue Supple Pages 1081-1084

DOI https://doi.org/10.2116/analsci.7.Supple_1081

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Abstract

Tributyltin(TBT) and triphenyltin compounds(TPT) in environmental and industrial waste waters were determined by gas chromatography with flame photometric detection using tripentyltin chloride(Pe₃SnCI) as a surrogate compound. Recoveries of TBT and TPT from These water samples was 96-108%, respectively and the standard deviations(R.S.D) were 2.2-9.8%, 1.4 7.4%, respectively. The detection limits were 2ng/l, far TBT(as tributyltin chloride) and 6ng/l for TPT(as triphenyltin chloride).

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