Analytical Sciences
Online ISSN : 1348-2246
Print ISSN : 0910-6340
ISSN-L : 0910-6340
Determination of Anions in Aqueous Solution by Measuring the Absorption of Radicals and Hydrated Electrons Using a UV Laser
Akyhiro IWATANobuaki NAKASHIMAYasukazu IZAWAChiyoe YAMANAKA
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1993 Volume 9 Issue 6 Pages 807-810

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Abstract
The determination of anions in aqueous solution using an ArF laser is described. Chloride ion can be determined down to a level of 4×10-7M by measuring the absorption of Cl formed by ArF laser irradiation using a multiple-reflection method with a helium-cadmium laser (λ=325nm) as the monitoring light source. Br-, I-, SCN-and SO42-were determined by measuring the absorption of radicals or hydrated electrons formed upon UV laser irradiation with detection limits of 4×10-7, 4×10-7, 1×10-6-and 1×10-4M, respectively.
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© The Japan Society for Analytical Chemistry
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