Crystal Structure of a Novel Binuclear Copper(II) Complex with 2-(Methoxycarbonyl)benzoic Acid

Tong-Huan LIU; Liang HUANG; Feng-Juan CHEN; Pin-Xian XI; Zhi-Hong XU; Min XU; Zheng-Zhi ZENG

doi:10.2116/analscix.24.x303

Part 13

Crystal Structure of a Novel Binuclear Copper(II) Complex with 2-(Methoxycarbonyl)benzoic Acid

Tong-Huan LIU, Liang HUANG, Feng-Juan CHEN, Pin-Xian XI, Zhi-Hong XU, Min XU, Zheng-Zhi ZENG

著者情報

Tong-Huan LIU
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University
Liang HUANG
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University
Feng-Juan CHEN
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University
Pin-Xian XI
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University
Zhi-Hong XU
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University
Min XU
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University
Zheng-Zhi ZENG
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University

ジャーナルフリー

2008 年 24 巻 p. x303-x304

DOI https://doi.org/10.2116/analscix.24.x303

詳細

抄録

A novel binuclear copper(II) complex with 2-(methoxycarbonyl)benzoic acid (HL), N,N-dimethylformamide (DMF) and methanol [Cu₂L₄(DMF)(CH₃OH)·CH₃OH] was synthesized. The complex was crystallized in the monoclinic system. The space group was Pn with a = 14.410(3)Å, b = 10.540(2)Å, c = 14.496(3)Å, β = 91.082(4)°, V = 2201.4(9)Å³ and Z = 2. The final R value was 0.0227. Each Cu(II) ion is coordinated by four carboxylate O donor atoms from four ligands, and by O donor atoms from the solvent molecule, DMF for Cu(1); for Cu(2) it is the O atom of methanol. The whole molecule looks like a “pedal-wheel”. The O-H…O hydrogen bonds between the compound and the solvent molecule stabilize the crystal structure by causing the formation of a one-dimensional chain structure.

責任著者(Corresponding author)

J-STAGEへの登録はこちら（無料）