The Journal of Antibiotics
Online ISSN : 1881-1469
Print ISSN : 0021-8820
ISSN-L : 0021-8820
REVISED STRUCTURE OF CERULENIN
BYRON H. ARISONSATOSHI OMURA
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1974 年 27 巻 1 号 p. 28-30

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An evaluation of the 100 MHz NMR spectrum strongly suggests that the structure of cerulenin is (2S) (3R) 2, 3-epoxy-4-oxo-7, 10-dodecadienoyl amide rather than the -6, 10-dodecadienoyl amide analog. This conclusion was experimentally supported by a spin-decoupling study in a benzene-chloroform mixed solvent system.

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© Japan Antibiotics Research Association
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