The Journal of Antibiotics
Online ISSN : 1881-1469
Print ISSN : 0021-8820
ISSN-L : 0021-8820
SYNTHESES OF 6'-C-AMINOMETHYL-3'-DEOXYPAROMAMINES
TAKASHI YAMAGUCHITSUTOMU TSUCHIYASUMIO UMEZAWA
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ジャーナル フリー

1977 年 30 巻 1 号 p. 71-75

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抄録
The first synthesis of 6'-C-aminomethyl derivatives (6'-epimers) of 3'-deoxyparomamine is reported starting from 3'-deoxyparomamine by way of 6'-O-tritylation, O-acetylation, hydrolysis of the trityl group, conversion of the 6'-hydroxyl group into an aldehyde group, nitromethane condensation of the aldehyde group and catalytic reduction of the nitro group into an amino group.
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© Japan Antibiotics Research Association
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