アジア・太平洋化学工学会議発表論文要旨集
Asian Pacific Confederation of Chemical Engineers congress program and abstracts
セッションID: 1A-12
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Kinetics of Liquid Penetration into Cast Tape
Boris GolmanTakashi TakigawaKunio ShinoharaKatsutomo Ohzeki
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The thin tapes are frequently used in modern applications to be filled with liquid into the void spaces among compacted particles. In the present study, the liquid penetration rate is measured for green and pressed tapes prepared under various cast parameters with graphite particles differing in original particle properties. In addition, an attempt is made to derive the penetration rate from the tape characteristics of porous micro-structure. The mathematical model of liquid penetration kinetics was developed, assuming the tape void space as the bundle of capillaries. The distribution of capillary diameters was defined as the distribution of void sizes measured by image analysis on the cross-section perpendicular to the tape surface. As a result, it was confirmed that the measured rate of liquid penetration into the tapes, which were prepared with various casting speeds, blade gaps and slurry concentrations, is mainly determined by the distribution of void sizes. The largest value of the penetration rate constant was obtained for the tape made of spherical particles followed by those manufactured with fibrous and flaky particles, as could be expected from the analysis of void size distributions. Penetration rates into layers of synthetic graphite particles were higher than in those made of natural particles possibly due to the difference in their contact angles.
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© 2004 The Society of Chemical Engineers, Japan
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