Synthesis of (±)-Methyl Bishomononactate, a Monomeric Component of Polynactin Antibiotics

Tadaatsu HANADATE; Hiromasa KIYOTA; Takayuki ORITANI

doi:10.1271/bbb.64.1671

Bioscience, Biotechnology, and Biochemistry

Online ISSN : 1347-6947
Print ISSN : 0916-8451

Organic Chemistry Regular Papers

Synthesis of (±)-Methyl Bishomononactate, a Monomeric Component of Polynactin Antibiotics

Tadaatsu HANADATE, Hiromasa KIYOTA, Takayuki ORITANI

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Keywords: total synthesis, iodoetherification, macrotetrolides, polynactin, antibiotics

JOURNAL FREE ACCESS

2000 Volume 64 Issue 8 Pages 1671-1674

DOI https://doi.org/10.1271/bbb.64.1671

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Abstract

The synthesis of (±)-methyl bishomononactate, one of the monomeric components of polynactin antibiotics (macrotetrolides), was achieved via cis-selective iodoetherification as the key step.

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