Bioscience, Biotechnology, and Biochemistry
Online ISSN : 1347-6947
Print ISSN : 0916-8451
Organic Chemistry
7-Hydroxyphthalide: A New Natural Salicylaldehyde Analog from Oulenzia sp. (Astigmata: Winterschmitiidae)
Nobuhiro SHIMIZUYasumasa KUWAHARA
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2001 年 65 巻 4 号 p. 990-992

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A new salicy lactone was detected from the unidentified Oulenzia sp. and its chemical structure was elucidated as 7-hydroxyphthalide (7-hydroxy-3 H-isobenzofuran-1-one), based on its GC/MS and GC/FT-IR data and SiO2 column behavior. The compound was synthesized by NaBH4 reduction of 3-hydroxyphthalic anhydride. The GC/MS and GC/FT-IR spectra of the natural compound were consistent with those of the synthetic product. Although the compound is known as a medical material, this is the first example of its presence in nature.
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© 2001 by Japan Society for Bioscience, Biotechnology, and Agrochemistry
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