Organic Chemistry
Synthesis of Macrotetrolide α, a Designed Polynactin Analog Composed of (+)- and (−)-Bishomononactic Acids
2001 年 65 巻 9 号 p. 2118-2120
詳細
2001 年 65 巻 9 号 p. 2118-2120
Macrotetrolide α, a designed analog of polynactin composed of (+)- and (−)-bishomononactic acids, was synthesized. These monomers were prepared via optical resoiution of the corresponding (S)-O-acetylmandelates. Assembly of the monomers to macrotetrolide α took seven steps without any loss of the intermediates.
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