Lipase-Catalyzed Kinetic Resolution of (±)-cis-Flavan-4-ol and Its Acetate: Synthesis of Chiral 3-Hydroxyflavanones

Tamotsu TODOROKI; Akiko SAITO; Akira TANAKA

doi:10.1271/bbb.66.1772

Bioscience, Biotechnology, and Biochemistry

Online ISSN : 1347-6947
Print ISSN : 0916-8451

Organic Chemistry Notes

Lipase-Catalyzed Kinetic Resolution of (±)-cis-Flavan-4-ol and Its Acetate: Synthesis of Chiral 3-Hydroxyflavanones

Tamotsu TODOROKI, Akiko SAITO, Akira TANAKA

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Keywords: kinetic resolution, lipase, 3-hydroxyflavanone

JOURNAL FREE ACCESS

2002 Volume 66 Issue 8 Pages 1772-1774

DOI https://doi.org/10.1271/bbb.66.1772

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Abstract

Lipase-catalyzed kinetic resolution of (±)-cis-flavan-4-ol and its acetate led to enantiomerically enriched flavan-4-ol and its acetate. These chiral compounds were converted to (2R, 3R)- and (2S, 3S)-3-hydroxyflavanones.

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