Isolation and Absolute Stereochemistry of Optically Active Sydonic Acid from Glonium sp. (Hysteriales, Ascomycota)

Shinji KUDO; Takanori MURAKAMI; Junsuke MIYANISHI; Kazuaki TANAKA; Noboru TAKADA; Masaru HASHIMOTO

doi:10.1271/bbb.80535

Bioscience, Biotechnology, and Biochemistry

Online ISSN : 1347-6947
Print ISSN : 0916-8451

Organic Chemistry Notes

Isolation and Absolute Stereochemistry of Optically Active Sydonic Acid from Glonium sp. (Hysteriales, Ascomycota)

Shinji KUDO, Takanori MURAKAMI, Junsuke MIYANISHI, Kazuaki TANAKA, Noboru TAKADA, Masaru HASHIMOTO

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Keywords: sydonic acid, optically active form, circular dichroism (CD) spectrum

JOURNAL FREE ACCESS

2009 Volume 73 Issue 1 Pages 203-204

DOI https://doi.org/10.1271/bbb.80535

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Abstract

Optically active sydonic acid (1) was isolated for the first time from a culture broth of Glonium sp. The absolute stereochemistry was established to be (S) by comparing the circular dichroism (CD) spectrum with that of (+)-curcutetraol after conversion into (+)-sydonol (2).

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