Bioscience, Biotechnology, and Biochemistry
Online ISSN : 1347-6947
Print ISSN : 0916-8451
Organic Chemistry Note
Stereoselective Synthesis of a Protected Form of (6R,7E,9S,10R,12Z)-6,9,10-Trihydroxy-7,12-hexadecadienoic Acid
Yusuke KURASHINAShigefumi KUWAHARA
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JOURNAL FREE ACCESS

2012 Volume 76 Issue 3 Pages 605-607

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Abstract

The protected stereoisomer of a trihydroxy unsaturated fatty acid, which could be employed as a potential nigricanoside α-chain building block, was synthesized by using Evans asymmetric alkylation, Sharpless kinetic resolution, and diastereoselective reduction as the key steps.

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© 2012 by Japan Society for Bioscience, Biotechnology, and Agrochemistry
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