Bulletin of the Agricultural Chemical Society of Japan
Online ISSN : 1881-1272
Print ISSN : 0375-8397
ISSN-L : 0375-8397
Studies on Sinomenine
Part LXVIII. (+)-Codeinone from Sinomenine
Kakuji GOTOIzuru YAMAMOTO
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1955 年 19 巻 2 号 p. 110-120

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A short survey of sinomenine investigation is given in the theoretical part, prin-cipally on the transformationn of sinomcnine of sinormenine derivatives, hitherto almost unnoticed in morphine derivatives, In experimental, the preparation of (+)-codeinone from sinomenine, reduction of I-bromocodeinone and similar compounds with SnCL2+HCL2, and the use of NaBH4 on the reduction of the ketonic group in sinomenine derivatives are described.
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© Japan Society for Bioscience, Biotechnology, and Agrochemistry
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