Bulletin of the Agricultural Chemical Society of Japan
Online ISSN : 1881-1272
Print ISSN : 0375-8397
ISSN-L : 0375-8397
Studies on Synthetic Pyrethroids
Part VIII. Addition of Ethyl Diazoacetate to Methyl α, β, δ-Trimethylsorbate
Yuzo INOUYEMinoru OHNO
著者情報
ジャーナル フリー

1956 年 20 巻 2 号 p. 77-79

詳細
抄録
Ethyl diazoacetate adds predominantly to the γδ-ethylenic bond of methyl α, β, δ-trimethylsorbate to yield the cyclopropane derivatives, which are shown by the isolation of (±)-cis-, and (±)-traps-caronic acids from ozonolysis and subsequent hypobromite oxidation of the adducts. One of the adduct acid, obtained crystalline m. p. 164-5°, is shown to be (±)-cis-3-(1'-methyl-2'-carboxypropenyl)-2, 2-dimethylcyclopropane-l-carboxylic acid both by spectroscopic and degrative evidence.
著者関連情報

この記事は最新の被引用情報を取得できません。

© Japan Society for Bioscience, Biotechnology, and Agrochemistry
前の記事 次の記事
feedback
Top