Agricultural and Biological Chemistry
Online ISSN : 1881-1280
Print ISSN : 0002-1369
ISSN-L : 0002-1369
A New Synthetic Method of Methyl Ketones
Part II. Acidic Cleavage and Ozonolysis Followed by Alkaline Cleavage of Alkyl Mesityl Oxide
Masanao MATSUIToshio YOSHIDA
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1964 年 28 巻 2 号 p. 105-113

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Alkyl mesityl oxides can be converted to methyl alkyl ketones such as methyl heptanone and hexa-hydropseudoionone by means of the two different methods, i.e., acidic cleavage and ozonolysis followed by alkaline cleavage. Thus, a new synthetic method of methyl ketones (RCH2COCH3) from alkyl halides (RX) has been established. The condensation of acetone with alkyl or alkenyl halide in liquid ammonia has been also described.
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© Japan Society for Bioscience, Biotechnology, and Agrochemistry
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