Agricultural and Biological Chemistry
Online ISSN : 1881-1280
Print ISSN : 0002-1369
ISSN-L : 0002-1369
Syntheses of γ-BHC Alkoxy Analogs
Makoto KISOKeiji TANAKAYuzuru SANEMITSUMasanori YOSHIDANorio KURIHARAMinoru NAKAJIMA
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1975 Volume 39 Issue 2 Pages 443-449

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Abstract
DL-(1245/36)*2-1-Akkoxy (methoxy, ethoxy and 2, 2, 2-trifluoroethoxy)-2, 3, 4, 5, 6-pentach-lorocyclohexanes were synthesized from (1234/56)-1, 4, 5, 6-tetrachloro-2, 3-epoxycyclohexane (α-BTC cis-epoxide). Meso-(1245/36)-3-alkoxy (methoxy, ethoxy and 2, 2, 2-trifluoroethoxy)-1, 2, 4, 5, 6-pentachlorocyclohexanes were synthesized from (1245/36)-3, 4, 5, 6-tetrachlorocyclo-hexane-1, 2-diol (α-BTC cis-diol).
DL-(1245/36)-3, 4, 5, 6-Tetrachloro-1, 2-dimethoxycyclohexane and meso-(1245/36)-1, 2, 4, 5-tetrachloro-3, 6-dimethoxycyclohexane were also prepared.
Hexa-O-methyl-muco-inositol was synthesized by the methylation of muco-inositol (1245/36-configuration).
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© Japan Society for Bioscience, Biotechnology, and Agrochemistry
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