抄録
DL-(1245/36)*2-1-Akkoxy (methoxy, ethoxy and 2, 2, 2-trifluoroethoxy)-2, 3, 4, 5, 6-pentach-lorocyclohexanes were synthesized from (1234/56)-1, 4, 5, 6-tetrachloro-2, 3-epoxycyclohexane (α-BTC cis-epoxide). Meso-(1245/36)-3-alkoxy (methoxy, ethoxy and 2, 2, 2-trifluoroethoxy)-1, 2, 4, 5, 6-pentachlorocyclohexanes were synthesized from (1245/36)-3, 4, 5, 6-tetrachlorocyclo-hexane-1, 2-diol (α-BTC cis-diol).
DL-(1245/36)-3, 4, 5, 6-Tetrachloro-1, 2-dimethoxycyclohexane and meso-(1245/36)-1, 2, 4, 5-tetrachloro-3, 6-dimethoxycyclohexane were also prepared.
Hexa-O-methyl-muco-inositol was synthesized by the methylation of muco-inositol (1245/36-configuration).
