Agricultural and Biological Chemistry
Online ISSN : 1881-1280
Print ISSN : 0002-1369
ISSN-L : 0002-1369
Base Catalysts in Phosphorylation by a New Phosphorylating Agent, MTBO
Masayoshi ETOMasayoshi IIOHideo MAEDAHirohisa OMURA
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1978 年 42 巻 2 号 p. 299-307

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Twenty amines were examined as catalysts for the phosphorylation of ribonucleoside by MTBO.
Primary n-alkyl and alicyclic amines were good catalysts giving the product in high yields. Branched-chain alkylamines were less effective than straight-chain alkylamines. While secondary amines were less effective than primary amines, the yields of the product were nearly equal to those with primary amines. Cyclic imines, except for morpholine, had high catalytic activities though the yields of the product were low. Tertiary amines were the least effective catalysts.
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© Japan Society for Bioscience, Biotechnology, and Agrochemistry
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