Stereoselective Synthesis of erythro-Serricornin, (4R, 6R, 7S)-, and (4596R, 75')-4?6-Dimethyl-7-hydroxynonan-3-one9 Stereoisomers of the Sex Pheromone of Cigarette Beetle
1981 年 45 巻 9 号 p. 2019-2023
詳細
1981 年 45 巻 9 号 p. 2019-2023
A stereoselective synthesis of erythro-serricornin [(4RS, 6R, 7S)-4, 6-dimethyl-7-hydroxynonan-3-one] was completed starting from L-(+)-tartaric acid. The relative configuration of C(6)-methyl and C(7)-hydroxyl groups in naturally occurring serricornin was threo.
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