Agricultural and Biological Chemistry
Online ISSN : 1881-1280
Print ISSN : 0002-1369
ISSN-L : 0002-1369
Anomeric Configuration Analysis-Extension of the Ring Oxygen Helicity Rule to Aromatic Glycofuranosides
Katsunori KOHATAHiroshi MEGURO
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1982 年 46 巻 8 号 p. 2077-2086

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A strong Cotton effect associated with the ring oxygen was studied in aromatic glycofuranosides. Phenyl and phenyl 1-thioglycofuranosides gave a strong band at 180nm and 200-210nm respectively, similar to the corresponding glycopyranosides, suggesting that the ring oxygen helicity rule can be extended to these aromatic glycofuranosides or the band can be used to determine their anomeric configurations and conformations.
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© Japan Society for Bioscience, Biotechnology, and Agrochemistry
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