Synthesis of ω-Chain-modified Analogues of T-Oxaprostaglandins
1984 年 48 巻 5 号 p. 1123-1129
詳細
1984 年 48 巻 5 号 p. 1123-1129
ω-Methyl- 11 -deoxy-7-oxaprostaglandin (5a-t), co-methyl-9, 11-bisdeoxy-7-oxaprostaglandin (6a-t) and their related compounds having a gem-dimethyl, gem-methylethyl, gem-methylpropyl, gem-methylbenzyl or gem-methylallyl group as the ω-chain (5b-5f, 6b-6e) were synthesized starting from cyclotene (1), 2-hydroxy-3-methyl-2-cyclopenten-1 -one, which is a principal constituent of coffee aroma and maple flavor.
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